Additions to and Substitutions at C-C &pgr;-Bonds, Volume 4 by M.F. Semmelhack PDF

By M.F. Semmelhack

ISBN-10: 0080405959

ISBN-13: 9780080405957

Quantity four specializes in additions and the ensuing substitutions at carbon-carbon &pgr;-bonds. half 1 comprises procedures commonly regarded as basic polar reactions, reactive electrophiles and nucleophiles including to alkenes and alkynes. an important subject is Michael-type addition to electron poor &pgr;-bonds, featured within the first six chapters. partially 2 are gathered the 4 common approaches resulting in nucleophilic fragrant substitution, together with radical chain approaches and transition steel activation via to &pgr;-complexation. Metal-activated addition (generally by way of nucleophiles) to alkenes and polyenes is gifted partly three, together with allylic alkylation catalyzed through palladium. The insurance of nonpolar additions partially four comprises radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.

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31 187. , 81 (1984) 5031. 188. , 67 (1987) 249. 189. , 19 (1988) 183. 190. , 23 (1992) 205. 191. , 14 (1981) 363. 192. , 66 (1970) 1680. 193. , 92 (1970) 4472. 194. , 97 (1975) 3632. 195. , 64 (1976) 1516. 196. , 43 (1965) $229. 197. Mulder, Thesis, Leiden, 1970. " 198. [157], p. 173. 199. , 32 (1960) 170. 200. , 94 (1990) 5435. This Page Intentionally Left Blank C. Pfirkfinyi (Editor) / TheoreticalOrganic Chemistry Theoretical and Computational Chemistry, Vol. V. All rights reserved Inter-Relations between VB & MO Theories for Organic H-Networks D.

Faraday Soc. 49 (1953) 1375. R. Pariser & R. G. Parr, I- Chem. Phys. 21 (1953) 466 & 767. 1. Koutecky, Chem. Phys. Lett. I (1967) 249. [31 ] J. Hubbard, Proc. Roy. Soc. A 272 (1963) 237 & 276 (1964) 238. [32] H. C. Longuet-Higgins & L. Salem, Proc. Roy. Soc. A 257 (1960) 445. J. N. MurreU & L. Salem, J. Chem. Phys. 34 ( 1961 ) 1914. [33] R. D. Poshusta, T. G. Schmalz & D. J. Klein, Mol. Phys. 66 (1989) 317. [34] I. Fischer-Hjalmers, J. Chem. Phys. 42 (1965) 1962. [35] IC F. Freed, J. Chem. Phys.

87 (1965)2045. [ 10] R. B. Woodward & R. Hoffmann, The Conservation of Orbital Symmetry, Springer-Chemie, Berlin, 1970. [11 ] D. J. Klein & N. ), Valence-Bond Theory and Chemical Structure, Elsevier, Amsterdam, 1990. [ 12] N. , in chap. 1, vol. III of Atomic Physics and Human Knowledge, Oxbow Press, Woodbridge, CT, 1963. [13] Plato, in chap. XXV of The Republic [translation F. C. Cornford], Oxford University Press, Oxford, 1941. [ 14] F. Harary, Graph Theory, Addison-Wesley, Reading, MA, 1969. [15] N.

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